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鹽霧試驗(yàn)機(jī)的鹽霧原理形成

發(fā)布時(shí)間：2012.04.20 新聞來(lái)源：http://www.xlenjoy.com 瀏覽次數(shù)：

鹽霧試驗(yàn)是一種主要利用鹽霧試驗(yàn)設(shè)備所創(chuàng)造的人工模擬鹽霧環(huán)境條件來(lái)考核產(chǎn)品或金屬材料耐腐蝕性能的環(huán)境試驗(yàn)。它分為二大類(lèi)，一類(lèi)為天然環(huán)境暴露試驗(yàn)，另一類(lèi)為人工加速模擬鹽霧環(huán)境試驗(yàn)。人工模擬鹽霧環(huán)境試驗(yàn)是利用一種具有一定容積空間的試驗(yàn)設(shè)備——【鹽霧試驗(yàn)箱機(jī)】，在其容積空間內(nèi)用人工的方法，造成鹽霧環(huán)境來(lái)對(duì)產(chǎn)品的耐鹽霧腐蝕性能質(zhì)量進(jìn)行考核。它與天然環(huán)境相比，其鹽霧環(huán)境的氯化物的鹽濃度，可以是一般天然環(huán)境鹽霧含量的幾倍或幾十倍，使腐蝕速度大大提高，對(duì)產(chǎn)品進(jìn)行鹽霧試驗(yàn)，得出結(jié)果的時(shí)間也大大縮短。如在天然暴露環(huán)境下對(duì)某產(chǎn)品樣品進(jìn)行試驗(yàn)，待其腐蝕可能要1年，而在人工模擬鹽霧環(huán)境條件下試驗(yàn)，只要24小時(shí)，即可得到相似的結(jié)果。

空氣中能容納一定量的水汽，氣溫愈高，空氣中所能容納的水汽愈多，反之愈少。當(dāng)空氣溫度低到不能容納原先所含有的水汽時(shí)，過(guò)剩的水汽便凝結(jié)成小水滴。沿海地區(qū)空氣中含有大量隨海水蒸發(fā)的鹽分，其溶于小水滴中便形成了濃度很高的鹽霧。鹽霧中的主要成分為NaC1，而NaC1 的溶液中是以Na+和C1－的形態(tài)存在的，由鹽霧技術(shù)研究的“集成電路的可靠性試驗(yàn)”得知鹽霧的沉積率與C1－的濃度成正比關(guān)系。所以在含鹽濃度高的海邊，其沉積率也很大，高濃度的鹽霧自然成為NaC1 溶液的載體。

通過(guò)試驗(yàn)可以知道，【鹽霧試驗(yàn)箱機(jī)】鹽霧的腐蝕作用受到溫度和鹽業(yè)濃度的影響，當(dāng)溫度在35 攝氏度，鹽液濃度在3%時(shí)其對(duì)物體的腐蝕(化學(xué)反應(yīng))作用最大。鹽霧中高濃度的(NaC1)迅速分解為Na+離子和活躍的C1－離子與分子式很活躍的金屬材料發(fā)生化學(xué)反應(yīng)生成強(qiáng)酸性的金屬鹽，其中的金屬離子與氧氣接觸后又還原生成較穩(wěn)定的金屬氧化物。

腐蝕是材料或其性能在環(huán)境的作用下引起的破壞或變質(zhì).大多數(shù)的腐蝕發(fā)生在大氣環(huán)境中,大氣中含有氧氣、濕度、溫度變化和污染物等腐蝕成分和腐蝕因素.鹽霧腐蝕就是一種常見(jiàn)和最有破壞性的大氣腐蝕.這里講的鹽霧是指氯化物的大氣,它的主要腐蝕成分是海洋中的氯化物鹽——氯化鈉,它主要來(lái)源于海洋和內(nèi)地鹽堿地區(qū).鹽霧對(duì)金屬材料表面的腐蝕是由于含有的氯離子穿透金屬表面的氧化層和防護(hù)層與內(nèi)部金屬發(fā)生電化學(xué)反應(yīng)引起的.同時(shí)，氯離子含有一定的水合能,易被吸附在金屬表面的孔隙、裂縫排擠并取代氯化層中的氧,把不溶性的氧化物變成可溶性的氯化物,使鈍化態(tài)表面變成活潑表面.造成對(duì)產(chǎn)品極壞的不良反應(yīng).

標(biāo)準(zhǔn)是對(duì)重復(fù)性事物和概述所做的統(tǒng)一規(guī)定。鹽霧試驗(yàn)標(biāo)準(zhǔn)是對(duì)鹽霧試驗(yàn)條件,如溫度、濕度、氯化鈉溶液濃度和PH值等做的明確具體規(guī)定,另外還對(duì)鹽霧試驗(yàn)箱性能提出技術(shù)要求。同種產(chǎn)品采用那種鹽霧試驗(yàn)標(biāo)準(zhǔn)要根據(jù)鹽霧試驗(yàn)的特性和金屬的腐蝕速度及對(duì)鹽霧的敏感程度選擇。下面介紹幾個(gè)鹽霧試驗(yàn)標(biāo)準(zhǔn),如GB/T2423.17—1993《電工電子產(chǎn)品基本環(huán)境試驗(yàn)規(guī)程試驗(yàn)Ka：鹽霧試驗(yàn)方法》,GB/T2423.18—2000《電工電子產(chǎn)品環(huán)境試驗(yàn) 第2部分：試驗(yàn) 試驗(yàn)Kb：鹽霧,交變(氯化鈉溶液)》,GB5938—86《輕工產(chǎn)品金屬鍍層和化學(xué)處理層的耐腐蝕試驗(yàn)方法》,GB/T1771—91《色漆和清漆耐中性鹽霧性能的測(cè)定》.

稱(chēng)重判定法是通過(guò)對(duì)腐蝕試驗(yàn)前后樣品的重量進(jìn)行稱(chēng)重的方法,計(jì)算出受腐蝕損失的重量來(lái)對(duì)樣品耐腐蝕質(zhì)量進(jìn)行評(píng)判,它特別適用于對(duì)某種金屬耐腐蝕質(zhì)量進(jìn)行考核;
腐蝕物出現(xiàn)判定法是一種定性的判定法,它以鹽霧腐蝕試驗(yàn)后,產(chǎn)品是否產(chǎn)生腐蝕現(xiàn)象來(lái)對(duì)樣品進(jìn)行判定,一般產(chǎn)品標(biāo)準(zhǔn)中大多采用此方法.

腐蝕數(shù)據(jù)統(tǒng)計(jì)分析方法提供了設(shè)計(jì)腐蝕試驗(yàn)、分析腐蝕數(shù)據(jù)、確定腐蝕數(shù)據(jù)的置信度的方法,它主要用于分析、統(tǒng)計(jì)腐蝕情況,而不是具體用于某一具體產(chǎn)品的質(zhì)量判定。

【鹽霧試驗(yàn)箱機(jī)】鹽霧試驗(yàn)的目的是為了考核產(chǎn)品或金屬材料的耐鹽霧腐蝕質(zhì)量,而鹽霧試驗(yàn)結(jié)果判定正是對(duì)產(chǎn)品質(zhì)量的宣判,它的判定結(jié)果是否正確合理,是正確衡量產(chǎn)品或金屬抗鹽霧腐蝕質(zhì)量的關(guān)鍵。鹽霧試驗(yàn)結(jié)果的判定方法有：評(píng)級(jí)判定法、稱(chēng)重判定法、腐蝕物出現(xiàn)判定法、腐蝕數(shù)據(jù)統(tǒng)計(jì)分析法。評(píng)級(jí)判定法是把腐蝕面積與總面積之比的百分?jǐn)?shù)按一定的方法劃分成幾個(gè)級(jí)別,以某一個(gè)級(jí)別作為合格判定依據(jù),它適合平板樣品進(jìn)行評(píng)價(jià)。

更多鹽霧試驗(yàn)箱機(jī)產(chǎn)品資料請(qǐng)瀏覽：http://www.xlenjoy.com/Product-321.html

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