汽車涂層抗酸蝕測(cè)試-鹽霧試驗(yàn)機(jī)

發(fā)布時(shí)間：2012.05.03 新聞來源：http://laohua.hjunkel.com 瀏覽次數(shù)：

人們十分關(guān)注酸雨對(duì)汽車涂層的破壞程度。一旦涂層表面材料被破壞，即形成了酸蝕。這種材料的破壞是由于涂層內(nèi)化學(xué)鍵發(fā)生酸促水解所形成的。當(dāng)大量聚合物分子鏈或分子的化學(xué)鍵發(fā)生斷裂，就會(huì)發(fā)生涂層脫落。因?yàn)?，在蒸發(fā)過程中酸在水滴邊緣凝結(jié)，使材料發(fā)生嚴(yán)重的破壞，從而形成了類似“環(huán)狀”或“水漬”圖案的酸蝕斑紋。

提高汽車涂層抗酸蝕研究的主要目的是開發(fā)出一種新的配方，可以提高高分子鏈結(jié)構(gòu)耐酸蝕性能。多數(shù)汽車涂層由高顏料組分的涂層（底漆）以及上面覆蓋的一層透明的面漆組成。以下介紹兩種測(cè)試方法：

BASF實(shí)驗(yàn)

曝露參數(shù)的量化
公司多年來一直在收集佛羅里達(dá)州杰克遜維爾曝露場(chǎng)的環(huán)境參數(shù)。基于這些數(shù)據(jù)，以下列出了研究加速酸蝕試驗(yàn)方法應(yīng)考慮的關(guān)鍵因素。

溫度
此前，公司已意識(shí)到杰克遜維爾戶外曝露結(jié)果中溫度的重要性。溫度參數(shù)參照曝露于杰克遜威爾的實(shí)際樣品的實(shí)時(shí)測(cè)量，并進(jìn)行了量化。在-../年，實(shí)測(cè)得高達(dá)012的樣品溫度。在3113 年，杰克遜威爾對(duì)在實(shí)際零件和測(cè)試樣板的戶外環(huán)境條件下的測(cè)量顯示，最高樣品溫度大約為432，，采用01 2作為加速測(cè)試中氙燈光照循環(huán)的黑板溫度。

雨水
公司的科學(xué)家認(rèn)為，必須使用含有特殊的化學(xué)成分和89 值的酸性溶液模擬杰克遜維爾的酸雨。從戶外觀察發(fā)現(xiàn)，小于的急陣雨和薄

濕度和潮濕時(shí)間
公司研究發(fā)現(xiàn)，保持與杰克遜威爾的自然曝露環(huán)境一致的相對(duì)濕度是必要的。這樣可以更好地模擬戶外長(zhǎng)時(shí)間的潮濕環(huán)境。杰克遜維爾氣候數(shù)據(jù)顯示，夏季的平均相對(duì)濕度約為80%（6-8 月）。

對(duì)佛羅里達(dá)州和其他地區(qū)潮濕時(shí)間（ABC）的研究顯示，戶外樣品一半以上的時(shí)間處于潮濕狀態(tài)，造成測(cè)試樣品潮濕的主要因素是露水。在杰克遜維爾的戶外觀察證實(shí)了這一觀點(diǎn)，發(fā)現(xiàn)多數(shù)夏季夜晚，露水在零件和樣板上產(chǎn)生凝露。一般來說，露水在第3 天早晨依然存在。

因此，在試驗(yàn)室加速測(cè)試中，在黑暗循環(huán)中噴淋純水用于模擬夜晚凝露。同時(shí)，在測(cè)試中保持80%的相對(duì)濕度以模擬杰克遜維爾的夏季環(huán)境。

樣品放置角度
在杰克遜維爾，當(dāng)曝露于戶外的樣板和零件被放置成水平或接近水平的角度時(shí)，可得到嚴(yán)重的酸蝕效果。通常來講，最嚴(yán)重的酸蝕出現(xiàn)在與水平成0-5度角的條件下。
為模擬最嚴(yán)酷的曝露條件，Q-SUN 試驗(yàn)箱的樣品架改造成與水平成1G角放置（普通Q-SUN 試驗(yàn)箱中的樣品架為與水平成-1G角放置）。

紫外線
根據(jù)Q-Panel 公司的經(jīng)驗(yàn)，要獲得與戶外結(jié)果對(duì)比的最佳相關(guān)性，實(shí)驗(yàn)室樣品應(yīng)曝露于與戶外類似的光譜能量分布（SPD）和類似強(qiáng)度的紫外光照下。Q-Panel 公司對(duì)陽光光譜的研究顯示，盡管日光光譜在一天中時(shí)刻都在改變，在夏日中午陽光最強(qiáng)時(shí)340nm 處的紫外光強(qiáng)為0.68/W2/m2.nm。結(jié)果對(duì)比

杰克遜維爾曝露場(chǎng)戶外測(cè)試數(shù)據(jù)
比較! 年的杰克遜維爾自然曝露數(shù)據(jù)以建立一條基線。如預(yù)期的一樣，每年的絕對(duì)數(shù)值都會(huì)有所不同。然而，每年各種不同樣品的排列順序都是完全一致的。

BASF公司的加速酸蝕測(cè)試效果
自200h 開始，每經(jīng)過100h 對(duì)測(cè)試樣品進(jìn)行評(píng)級(jí)。在Q-SUN中曝露200h 后，樣品性能的相對(duì)排列順序基本確立，并在曝露試驗(yàn)過程中保持不變。

布朗特島曝露試驗(yàn)及加速酸蝕測(cè)試

布朗特島曝露試驗(yàn)
佛羅里達(dá)州杰克遜威爾的布朗特島在夏季一直是北美洲酸雨最嚴(yán)重的地區(qū)之一。因此，該地成為多種汽車涂層抗酸蝕性能評(píng)估的戶外測(cè)試場(chǎng)。每年都有汽車制造商及其供應(yīng)商將大量的車篷、面板和儀表板放在杰克遜維爾進(jìn)行測(cè)試。車篷、面板和儀表板的尺寸和形狀各異，但最常見的是黑色，用以得到最嚴(yán)酷的酸蝕結(jié)果。選擇的測(cè)試方法有多種，但通常是放置在與水平成0-5度角進(jìn)行測(cè)試。典型的測(cè)試周期大約是14個(gè)星期，在每年的6-9月進(jìn)行。測(cè)試樣品在這$B 個(gè)星期內(nèi)的每個(gè)星期都進(jìn)行酸蝕損失的評(píng)定，評(píng)定采用目測(cè)方法，即用一塊標(biāo)準(zhǔn)面板作為對(duì)照。

布朗特島曝露是真實(shí)的戶外實(shí)際測(cè)試，是準(zhǔn)確可靠的。但對(duì)產(chǎn)品開發(fā)卻存有明顯的局限性。除了因測(cè)試的地理位置和時(shí)間的局限外，測(cè)試還會(huì)因每年氣候條件的不同而得到不同的測(cè)試結(jié)果。

加速酸蝕測(cè)試
對(duì)汽車面漆抗酸蝕能力的實(shí)驗(yàn)室加速試驗(yàn)已經(jīng)進(jìn)行了許多研究。當(dāng)前本行業(yè)所使用的方法有梯度棒測(cè)試、酸浸蝕測(cè)試等。沒有一種測(cè)試能包含所有導(dǎo)致汽車面漆酸蝕的實(shí)際參數(shù)，如濕度、紫外線、樣品朝向、酸液組成等。

更多鹽霧試驗(yàn)機(jī)產(chǎn)品資料請(qǐng)瀏覽：http://www.xlenjoy.com/Product-321.html

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汽車涂層抗酸蝕測(cè)試,鹽霧試驗(yàn)機(jī),腐蝕試驗(yàn)箱佛山翁開爾

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